期刊
CARBON
卷 146, 期 -, 页码 88-96出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2019.01.064
关键词
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资金
- Deakin University
- Australian Research Council discovery programme [DP180100094]
- ARC Centre for Future Fibers [IH140100018]
- ARC Training Centre for Lightweight Automotive Structures [IC160100032]
- Office of Naval Research Global [N62909-18-1-2024]
- CSIRO
- Australian Government
- Government of Western Australia
This paper examines the effect on interfacial shear strength (IFSS) when grafting polyethyleneoxide (PEO) polymers of various molecular weights to a carbon fiber surface. Using copper-azide-alkyne cycloaddition click chemistry, PEO polymers of 1 kDa, 2 kDa, 5 kDa, and 10 kDa were tethered to the fiber surface without causing degradation of the fiber surface. The resulting IFSS increases were maximised (130% and 160%) for the 1 kDa and 10 kDa surface modified fibers, respectively. These data suggest that increases in IFSS are the result of an interplay between the density of surface modification versus the penetration of the grafted polymer into the matrix interphase. The trade-off between interphase penetration and surface grafting density is highlighted for the 2 and 5 kDa PEO chains on the fiber surface which display smaller IFSS increases (85% and 117%, respectively). Measuring the mobility of the PEO polymers by H-1 NMR found an order of magnitude decrease in diffusion coefficient for each successive increase in molecular weight, supporting the hypothesis that grafting density decreases with molecular weight. Molecular dynamics simulations of the carbon fiber-matrix interface further supports these observations. These results will inform the design of complementary interfaces for various materials in a range of supporting media. Crown Copyright (c) 2019 Published by Elsevier Ltd. All rights reserved.
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