期刊
CARBON
卷 146, 期 -, 页码 60-69出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2019.01.103
关键词
-
资金
- National Key Research and Development Program of China [2016YFB0600305]
- National Natural Science Foundation of China [21306132, 21476168]
A series of metal-free N-doped carbon nanotubes (NCNTs) are synthesized using melanin or protoporphyrin IX as the dopant via a pyrolysis process. Multiwalled carbon nanotubes with various diameters are employed as the support, and their performance is compared with those of graphene and carbon black. The content of doped graphitic N is effectively controlled by varying the heating rate during pyrolysis. The obtained metal-free catalysts are employed to catalyze the hydrogenation of various nitroarenes under mild reaction conditions (2 MPa of H-2, 120 degrees C). Efficient and selective hydrogenation of 14 nitroarenes is achieved over NCNTs with outer diameters of <= 20 nm synthesized via pyrolysis of melanin at 800 degrees C. Graphitic N in the as-prepared NCNTs is found to play a key role in efficient hydrogenation. Kinetic data reveal that a zero-order reaction occurs on the NCNTs, and the apparent activation energy of 4-nitrophenol hydrogenation is as low as 35.69 kJ mol(-1). Recycling experiments indicate that the NCNTs have good stability and recyclability for hydrogenation of 4-nitrophenol. (c) 2019 Elsevier Ltd. All rights reserved.
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