期刊
APPLIED SURFACE SCIENCE
卷 475, 期 -, 页码 151-157出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2018.12.116
关键词
Graphene oxide; Li adsorption; First-principles calculations
类别
资金
- Mid-career Researcher Program [NRF-2018R1A2B6005159]
- Nano-Material Technology Development Program [NRF-2014M3A7B4049367]
- Basic Research Laboratory through the National Research Foundation of Korea - Ministry of Science, ICT & Future Planning [NRF-2014R1A4A1071686]
Density functional theory based calculations are used to investigate the energetically and dynamically most stable structure for a crystalline unzipped graphene oxide (UGO) monolayer by considering parallel or anti-parallel dipolar structures. The O atom in the UGO monolayer induces electron excessive and deficient regions, which makes Li-ions selectively trapped in the electron deficient region. Apart from this, the periodic injection of O in graphene (C4O) opens a small band gap (0.6 eV) while keeps the Dirac cone. The adsorption of Li-ions makes it metallic by donating an extra electron to the UGO monolayer. The UGO monolayer can have a high Li storage capacity of 419 mAh/g and a typical anodic open circuit voltage range of 0.94-0.19 V. The energy barrier for Li migration is almost double of the pristine graphene, which results from the localized positive charge regions in the UGO monolayer.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据