期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 29, 页码 9816-9819出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201904899
关键词
arylation; C-C bond activation; enolonium species; ketones; umpolung
资金
- University of Vienna
- ERC
- FWF [P30226]
A synthetically useful approach for the direct alpha-arylation of carbonyl compounds through a novel oxidative C-C bond activation is reported. This mechanistically unusual process relies on a 1,2-aryl shift and results in all-carbon quaternary centers. The transformation displays broad functional-group tolerance and can in principle also be applied as an asymmetric variant.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据