期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 21, 页码 7025-7029出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201902188
关键词
alkynes; DFT; hydroboration; magnesium; vinyl borane
A magnesium-catalyzed hydroboration of alkynes providing good yields and selectivities for a wide range of terminal and symmetrical and unsymmetrical internal alkynes has been developed. The compatibility with many functional groups makes this magnesium catalyzed procedure attractive for late stage functionalization. Experimental mechanistic investigations and DFT calculations reveal insights into the reaction mechanism of the magnesium catalyzed protocol.
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