期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 24, 页码 8058-8062出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201902595
关键词
carbon nanotubes; endohedral metallofullerene; HRTEM; hybrid materials; Raman spectroscopy
资金
- Deutsche Forschungsgemeinschaft (DFG, German Research Foundation) [182849149-SFB 953]
- Alexander von Humboldt (AvH) Fundation
- National Key Research and Development Program of China [2017YFA0402800]
Using a reductive sidewall functionalization concept, we prepared for the first time a covalent inter-carbon-allotrope hybrid consisting of single-walled carbon nanotubes (SWCNTs) and the endohedral fullerene Sc3N@C-80. The new compound type was characterized through a variety of techniques including absorption spectroscopy, Raman spectroscopy, TG-MS, TG-GC-MS, and MALDI-TOF MS. HRTEM investigations were carried out to visualize this highly integrated architecture.
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