期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 23, 页码 7792-7796出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201903384
关键词
allenes; cascade reactions; C-H functionalization; cyclopropanation; gold
资金
- JSPS KAKENHI [JP15KT0061, JP17H03971, JP18H04408]
- Basis for Supporting Innovative Drug Discovery and Life Science Research (BINDS) from AMED, Japan [JP18am0101092j0001]
- Hoansha Foundation
A gold-catalyzed reaction of phenylene-tethered allenynes with benzofurans gave 1-(naphth-1-yl)cyclopropa[b]benzofuran derivatives, whereas the reaction of 1-allenyl-2-ethynyl-3-methylbenzene derivatives in the absence of benzofurans gave acenaphthenes in good yields. These results can be rationalized by nucleophilic attack of the alkyne moiety on an activated allene to form a vinyl cation intermediate.
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