期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 29, 页码 9820-9825出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201902258
关键词
C-H activation; meta selectivity; photocatalysis; remote C-H functionalization; ruthenium
资金
- Alexander von Humboldt Foundation
- DAAD
- DFG [SPP1807]
Visible-light-induced ruthenium catalysis has enabled remote C-H alkylations with excellent levels of position control under exceedingly mild conditions at room temperature. The metallaphotocatalysis occurred under exogenous-photosensitizer-free conditions and features an ample substrate scope. The robust nature of the photo-induced mild meta-C-H functionalization is reflected by the broad functional group tolerance, and the reaction can be carried out in an operationally simple manner, setting the stage for challenging secondary and tertiary meta-C-H alkylations by ruthenaphotoredox catalysis.
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