期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 30, 页码 10189-10193出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201903878
关键词
catalyst activation; catalyst deactivation; concentration reaction profiles; kinetics; variable time normalization analysis
资金
- EPSRC [EP/S005315/1, EP/P007589/1, EP/K039547/1, EP/N509681/1]
- MINECO [CTQ2017-89814-P]
- ICIQ Foundation
- RSC
- EPSRC [EP/P007589/1, EP/S005315/1, EP/K039547/1, 1803783] Funding Source: UKRI
Progress reaction profiles are affected by both catalyst activation and deactivation processes occurring alongside the main reaction. These processes complicate the kinetic analysis of reactions, often directing researchers toward incorrect conclusions. We report the application of two kinetic treatments, based on variable time normalization analysis, to reactions involving catalyst activation and deactivation processes. The first kinetic treatment allows the removal of induction periods or the effect of rate perturbations associated with catalyst deactivation from kinetic profiles when the quantity of active catalyst can be measured. The second treatment allows the estimation of the activation or deactivation profile of the catalyst when the order of the reactants for the main reaction is known. Both treatments facilitate kinetic analysis of reactions suffering catalyst activation or deactivation processes.
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