期刊
ANALYTICAL CHEMISTRY
卷 91, 期 13, 页码 8358-8365出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.analchem.9b01152
关键词
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资金
- Ministry of Science and Technology, Taiwan [MOST 107-2113-M-027-005-MY3]
- Advanced Research Center for Green Materials Science and Technology from The Featured Area Research Center Program within the framework of the Higher Education Sprout Project by the Ministry of Education [107L9006]
- Ministry of Science and Technology in Taiwan [MOST 105-2221-E-002-229-MY3, 107-2811-E-002-559, 107-3017-F-002-001]
The presence of defect/distortion on layered structure of metal chalcogenides facilitate the higher electronic conductivity and electrocatalytic activity. In this work, we have successfully synthesized Co-doped MoSe2(CoMoSe2, Co2MoSe2, Co3MoSe2, and Co4MoSe2) in 1T phase crystal structure by using hydrothermal technique and integrated with graphene oxide (GO). Various analytical techniques such as TEM, STEM, FESEM, XRD, RAMAN, EDX, ICP, and XPS confirmed the formation of IT phase and defective sites on Co-doped MoSe2. Consequently, the relevant electrochemical studies were followed and reported the significant enhancement in electrocatalytic activity of MoSe2 due to the Co doping and GO hybridization. The proposed GO@CoMoSe2 electrocatalyst was developed to electrode material for electrochemical sensor and supercapacitor applications. As expected, the GO@CoMoSe2 modified glassy carbon electrode exhibited an excellent electrocatalytic activity toward the sensing of Metol (LOD, 0.009 mu M; sensitivity, 2.397 mu A mu M-1 cm(-2)). Meanwhile, GO@CoMoSe2-coated nickel foam (NF) achieved feasible specific capacity (431.47 C g(-1)). In addition, the GO@CoMoSe2//AC asymmetric device exhibited the feasible energy density of 58.32 W h kg(-1) at power density of 1800.25 W kg(-1). Thus, we concluded that the Co doping and GO hybridization with MoSe2 provide the interesting idea to find out the excellent electrocatalysts with improved electrochemical performances toward the sensing and battery type supercapacitor applications.
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