期刊
CHEM
卷 5, 期 5, 页码 1182-1193出版社
CELL PRESS
DOI: 10.1016/j.chempr.2019.02.012
关键词
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资金
- Ministry of Science and Technology of China [2016YFA0200101, 2016YFA0200104]
- National Natural Science Foundation of China [51432002, 21790052, 51720105003]
- Beijing Municipal Science and Technology Planning Project [Z161100002116026]
- China Postdoctoral Science Foundation [8201400852, 8201400892]
- Institute for Basic Science for South Korea [IBS-R019-D1]
- Natural Science Foundation of Shandong Province of China [ZR2016EMM10]
Semiconducting single-walled carbon nanotubes (SWNTs) with controlled chirality (n, m) and band gaps are expected to create a new era of electronics. Here, we report a rational design to enable SWNTs' near-equilibrium nucleation and then grow a new family of semiconducting SWNTs: (n, n - 1) carbon nano-tubes. No metallic SWNTs were observed in similar to 100 samples by reflection optical spectral measurements. Combined with catalyst controlling, we have successfully synthesized both large-diameter (>2 nm) (n, n - 1) SWNTs and single-chirality (10, 9) SWNTs with abundances of 88% and >80%, respectively. Theoretical analysis indicates that the chirality of (n, n) tubes tends to change to (n, n - 1) by kinetically incorporating an energetically preferred pentagon-heptagon pair in the tube wall. This strategy opens up a new route for the growth of SWNT families beyond catalyst design.
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