期刊
ADVANCED SCIENCE
卷 6, 期 6, 页码 -出版社
WILEY
DOI: 10.1002/advs.201802130
关键词
chloride ion batteries; electrochemistry; iron oxychloride; polymer electrolytes; rechargeable batteries
资金
- National Natural Science Foundation of China [U1407106, 51674147]
- Natural Science Foundation of the Jiangsu Higher Education Institutions [16KJA430001]
- Natural Science Foundation of Jiangsu Province [BK20161544]
- QingLan Project of Jiangsu Province
- Priority Academic Program Development of Jiangsu Higher Education Institutions [PAPD]
The chloride ion battery has been developed as one of the alternative battery chemistries beyond lithium ion, toward abundant material resources and high energy density. Its application, however, is limited by the dissolution of electrode materials and side reactions in the liquid electrolyte. Herein, a solid polymer electrolyte allowing chloride ion transfer and consisting of poly(ethylene oxide) as the polymer matrix, tributylmethylammonium chloride as the chloride salt, and succinonitrile as the solid plasticizer is reported. The as-prepared polymer electrolyte shows conductivities of 10(-5)-10(-4) S cm(-1) in the temperature range of 298-343 K. When it is assembled with the iron oxychloride/lithium electrode system, reversible electrochemical redox reactions of FeOCl/FeO at the cathode side and Li/LiCl at the anode side are realized, demonstrating the first all-solid-state rechargeable chloride ion battery.
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