期刊
NANOMATERIALS
卷 9, 期 3, 页码 -出版社
MDPI
DOI: 10.3390/nano9030467
关键词
metal-organic framework; gas separation; machine learning; molecular simulation; linear dimension reduction
类别
资金
- National Natural Science Foundation of China [21676094, 21576058, 21676060, 21706197]
The Monte Carlo and molecular dynamics simulations are employed to screen the separation performance of 6013 computation-ready, experimental metal-organic framework membranes (CoRE-MOFMs) for 15 binary gas mixtures. After the univariate analysis, principal component analysis is used to reduce 44 performance metrics of 15 mixtures to a 10-dimension set. Then, four machine learning algorithms (decision tree, random forest, support vector machine, and back propagation neural network) are combined with k times repeated k-fold cross-validation to predict and analyze the relationships between six structural feature descriptors and 10 principal components. Based on the linear correlation value R and the root mean square error predicted by the machine learning algorithm, the random forest algorithm is the most suitable for the prediction of the separation performance of CoRE-MOFMs. One descriptor, pore limiting diameter, possesses the highest weight importance for each principal component index. Finally, the 30 best CoRE-MOFMs for each binary gas mixture are screened out. The high-throughput computational screening and the microanalysis of high-dimensional performance metrics can provide guidance for experimental research through the relationships between the multi-structure variables and multi-performance variables.
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