期刊
METALS
卷 9, 期 2, 页码 -出版社
MDPI
DOI: 10.3390/met9020222
关键词
CeO2; microstructure; magnetic properties; Mossbauer spectrometry
资金
- ERDF/ESF New Composite Materials for Environmental Applications by Ministry of Education, Youth and Sports of the Czech Republic [CZ.02.1.01/0.0/0.0/17_048/0007399]
- CEITEC 2020 - National Sustainability Programme II by Ministry of Education, Youth and Sports of the Czech Republic [LQ1601, SP2018/43]
- National Science Centre of Poland [2015/19/B/ST8/02636]
CeO2 samples prepared by three technological procedures from the same cerium source, namely cerium (III) nitrate hexahydrate, are studied from the viewpoint of structure, chemical and phase composition, and micro- and macro-magnetic properties. The scanning and transmission electron microscopies completed by energy-dispersive X-ray (EDX) analysis yield nano-structural natures and homogenous chemical compositions of the ceria samples, confirmed also by X-ray diffraction. The diamagnetic, paramagnetic, and ferromagnetic phases in all samples follow from an analysis of the room- and low-temperature measurements of hysteresis loops. Iron impurities in ppm amounts are clearly detected by Fe-57 Mossbauer spectrometry not only in the ceria samples but also in the selected input chemicals used for their preparation. This contributes to the explanation of the magnetic behaviour of nanosized ceria.
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