期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 7, 期 6, 页码 5690-5697出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.8b04727
关键词
Carbon dioxide utilization; Dry reforming of methane; Ni catalyst; Surface protonics
资金
- KAKENHI [17H07194]
- Grants-in-Aid for Scientific Research [17H07194] Funding Source: KAKEN
The role of the electric field and surface protonics on low temperature catalytic dry reforming of methane was investigated over 1 wt % Ni/10 mol %La-ZrO2 catalyst, which shows very high catalytic activity even at temperatures as low as 473 K. We investigated kinetic analyses using isotope and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), and kinetic analyses revealed synergetic effects between the catalytic reaction and the electric field with less than one-fifth the apparent activation energy at low reaction temperatures. Results of kinetic investigations using isotopes such as CD4 and O-18(2), in situ DRIFTS in the electric field, and density functional theory calculation indicate that methane dry reforming proceeds well by virtue of surface protonics. CH4 and CO2, were activated by proton collision at the Ni La-ZrO2 interface based on the inverse kinetic isotope effect.
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