期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 34, 页码 9872-9876出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201601252
关键词
charge transfer; fluorescence; naphthalimides; organic dyes; phosphorescence
资金
- Fundamental Research Funds for the Central Universities [WK2340000068, CX2060200022]
- National Natural Science Foundation of China [21222405, 51402282]
Purely organic materials with room-temperature phosphorescence (RTP) are currently under intense investigation because of their potential applications in sensing, imaging, and displaying. Inspired by certain organometallic systems, where ligand-localized phosphorescence ((3)pi-pi*) is mediated by ligand-to-metal or metal-to-ligand charge transfer (CT) states, we now show that donor-to-acceptor CT states from the same organic molecule can also mediate pi-localized RTP. In the model system of N-substituted naphthalimides (NNIs), the relatively large energy gap between the NNI-localized 1 pi-pi* and (3)pi-pi* states of the aromatic ring can be bridged by intramolecular CT states when the NNI is chemically modified with an electron donor. These NNI-based RTP materials can be easily conjugated to both synthetic and natural macromolecules, which can be used for RTP microscopy.
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