期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 9, 页码 3187-3191出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201511624
关键词
alkenes; C-H functionalization; heterocycles; iron; silver
资金
- Natural Science Foundation of China [21472039, 21172060]
- Hunan Provincial Natural Science Foundation of China [13JJ2018]
A new iron-facilitated silver-mediated radical 1,2-alkylarylation of styrenes with -carbonyl alkyl bromides and indoles is described, and two new C-C bonds were generated in a single step through a sequence of intermolecular C(sp(3))-Br functionalization and C(sp(2))-H functionalization across the alkenes. This method provides an efficient access to alkylated indoles with broad substrate scope and excellent selectivity.
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