期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 21, 页码 6275-6279出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201511975
关键词
alkenes; alkynes; copper; cross-coupling; palladium
资金
- MEXT [26810058]
- CREST program Establishment of Molecular Technology towards the Creation of New Functions Area from JST
- Grants-in-Aid for Scientific Research [26810058] Funding Source: KAKEN
A method for the reductive cross-coupling of conjugated arylalkenes and aryl bromides with hydrosilanes by cooperative palladium/copper catalysis was developed, thus resulting in the highly regioselective formation of various 1,1-diarylalkanes, including a biologically active molecule. Under the applied reaction conditions, high levels of functional-group tolerance were observed, and the reductive cross-coupling of internal alkynes with aryl bromides afforded trisubstituted alkenes.
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