期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 50, 页码 15599-15603出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201609073
关键词
chirality-assisted synthesis; encapsulation; hostguest chemistry; NMR spectroscopy; tribenzotriquinacenes
资金
- Fonds de recherche du Quebec-Nature et technologies
The strategy of chirality-assisted synthesis, which makes use of enantiomerically pure building blocks that are designed to associate in a single geometric orientation, was applied to synthesize an octameric hydrogen-bonded capsule with a cavity volume of 2300 angstrom(3). This cube-shaped capsule forms even host-guest complexes with tetraalkylammonium ions, and accommodates the large tetrahexadecylammonium cation in its cavity. The use of an enantiopure building block was shown to be highly beneficial for capsule formation, whereas its racemate also generates a large amount of illdefined aggregates in solution and crystallizes as a hydrogenbonded network.
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