期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 27, 页码 7751-7755出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201601999
关键词
C-H activation; olefination; palladium; silicon; synthetic methods
资金
- SERB [EMR/2015/000164]
- UGC India
- DST
- CSIR India
Various practical methods for the selective C-H functionalization of the ortho and recently also of the meta position of an arene have already been developed. Following our recent development of the directing-group-assisted para C-H functionalization of toluene derivatives, we herein report the first remote para C-H functionalization of phenol derivatives by using a recyclable silicon-containing biphenylbased template. The effectiveness of this strategy was illustrated with different synthetic elaborations and by the synthesis of various phenol-based natural products.
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