期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 26, 页码 7408-7412出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201601778
关键词
C-C cleavage; C-H activation; cobalt; homogeneous catalysis; stereoselectivity
资金
- European Research Council under the European Community/ERC [307535]
- DFG (SPP 1807)
- CSC
Cationic cobalt complexes enable unprecedented cobalt-catalyzed C-H/C-C functionalizations with unique selectivity features. The versatile cobalt catalyst proved broadly applicable, enabled efficient C-H/C-C cleavage at room temperature, and delivered Z-alkenes with excellent diastereocontrol.
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