期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 15, 页码 4803-4807出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201511179
关键词
Bronsted acids; carbenium ions; Michael addition; ortho-quinone methides; substitution
资金
- DFG (Deutsche Forschungsgemeinschaft) through the International Research Training Group SeleCa [IRTG 1628]
- DAAD
- JSPS (Japanese Society for the Promotion of Science) through the Japanese-German Graduate Externship
An enantioselective addition of thiols and alcohols to aza-ortho-quinone methides, starting from diaryl methanols, was developed. The asymmetric additions occur under mild reaction conditions in the presence of chiral phosphoric acids and furnish the corresponding adducts with excellent yields and enantioselectivities.
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