期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 11, 页码 3566-3579出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201506219
关键词
charge transport; conductivity; devices; metal-organic frameworks; porous materials
资金
- Department of Energy (DOE) through Center for Excitonics, an Energy Frontier Research Center
- DOE Office of Science, Office of Basic Energy Sciences [DE-SC0006937, DE-SC0001088]
- 3M
- Sloan Foundation
- Research Corporation for Science Advancement
- Dreyfus Foundation
- Young Investigator Award
Owing to their outstanding structural, chemical, and functional diversity, metal-organic frameworks (MOFs) have attracted considerable attention over the last two decades in a variety of energy-related applications. Notably missing among these, until recently, were applications that required good charge transport coexisting with porosity and high surface area. Although most MOFs are electrical insulators, several materials in this class have recently demonstrated excellent electrical conductivity and high charge mobility. Herein we review the synthetic and electronic design strategies that have been employed thus far for producing frameworks with permanent porosity and long-range charge transport properties. In addition, key experiments that have been employed to demonstrate electrical transport, as well as selected applications for this subclass of MOFs, will be discussed.
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