期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 41, 页码 12736-12740出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201605936
关键词
green chemistry; main-group chemistry; mechanochemistry; phosphazanes; rearrangements
资金
- NTU [M4080552]
- MOE [M4011441]
- Australian Research Council
- McGill University
All reported attempts to synthesize the tert-butyl-substituted adamantoid phosph(III)azane P-4((NBu)-Bu-t)(6) have failed, leading to the classification of this molecule as inaccessible and a literature example of steric control in chemistry of phosphorus-nitrogen compounds. We now demonstrate that this structure is readily accessible by a solvent-free mechanochemical milling approach, highlighting the importance of mechanochemical reaction environments in evaluating chemical reactivity.
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