期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 12, 页码 4087-4091出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201509382
关键词
heterogeneous catalysts; metal nanoparticles; nanostructured materials; oxygen reduction; water oxidation
资金
- DFG (Deutsche Forschungsgemeinschaft) [EXC1069]
Efficient reversible oxygen electrodes for both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) are vitally important for various energy conversion devices, such as regenerative fuel cells and metal-air batteries. However, realization of such electrodes is impeded by insufficient activity and instability of electrocatalysts for both water splitting and oxygen reduction. We report highly active bifunctional electrocatalysts for oxygen electrodes comprising core-shell Co@Co3O4 nanoparticles embedded in CNT-grafted N-doped carbon-polyhedra obtained by the pyrolysis of cobalt metal-organic framework (ZIF-67) in a reductive H-2 atmosphere and subsequent controlled oxidative calcination. The catalysts afford 0.85V reversible overvoltage in 0.1m KOH, surpassing Pt/C, IrO2, and RuO2 and thus ranking them among one of the best non-precious-metal electrocatalysts for reversible oxygen electrodes.
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