期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 3, 页码 753-756出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201608924
关键词
all-solid-state battery; interfacial resistance; Li-rich garnet; Li-S battery; lithium fluoride
资金
- National Science Foundation [CBET-1438007]
- U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DESC0005397]
- Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies of the U.S. Department of Energy through the Advanced Battery Materials Research (BMR) Program
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [1438007] Funding Source: National Science Foundation
Li7La3Zr2O12-based Li-rich garnets react with water and carbon dioxide in air to form a Li-ion insulating Li2CO3 layer on the surface of the garnet particles, which results in a large interfacial resistance for Li-ion transfer. Here, we introduce LiF to garnet Li6.5La3Zr1.5Ta0.5O12 (LLZT) to increase the stability of the garnet electrolyte against moist air; the garnet LLZT-2 wt% LiF (LLZT-2LiF) has less Li2CO3 on the surface and shows a small interfacial resistance with Li metal, a solid polymer electrolyte, and organic-liquid electrolytes. An all-solid-state Li/polymer/LLZT-2LiF/ LiFePO4 battery has a high Coulombic efficiency and long cycle life; a Li-S cell with the LLZT-2LiF electrolyte as a separator, which blocks the polysulfide transport towards the Li-metal, also has high Coulombic efficiency and kept 93% of its capacity after 100 cycles.
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