期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 27, 页码 7786-7791出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201511695
关键词
carbonates; glycoconjugates; glycosidation; gold catalysis; oligosaccharides
资金
- CSIR-UGC-NET
- DST, New Delhi
- Swarnajayanthi Fellowship
Oligosaccharide synthesis is still a challenging task despite the advent of modern glycosidation techniques. Herein, alkynyl glycosyl carbonates are shown to be stable glycosyl donors that can be activated catalytically by gold and silver salts at 25 degrees C in just 15 min to produce glycosides in excellent yields. Benzoyl glycosyl carbonate donors are solid compounds with a long shelf life. This operationally simple protocol was found to be highly efficient for the synthesis of nucleosides, amino acids, and phenolic and azido glycoconjugates. Repeated use of the carbonate glycosidation method enabled the highly convergent synthesis of tridecaarabinomannan in a rapid manner.
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