期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 13, 页码 4322-4326出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201600148
关键词
allylic compounds; asymmetric catalysis; multicomponent reactions; palladium; phase-transfer catalysis
资金
- MOST (973 project) [2015CB856600]
- NSFC [21232007]
- SRG-HSC [2015SRG-HSC044]
A highly selective multicomponent carbonyl allylation reaction of 1,3-butadienes, aryldiazonium tetrafluoroborates, and aldehydes has been established under the combined catalysis of palladium acetate and chiral anion phase transfer to render the favorable assembly of chiral Z-configured homoallylic alcohols in high yields and with excellent levels of enantioselectivity.
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