期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 1, 页码 60-95出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201604731
关键词
crystal growth; metals; nanoparticles; nucleation; properties control
资金
- NSF [DMR-1215034, DMR-1506018, CHE-1505441]
- NCI [R01 CA138527]
- NIH
- Georgia Institute of Technology
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1505441] Funding Source: National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1505400] Funding Source: National Science Foundation
Seed-mediated growth is a powerful and versatile approach for the synthesis of colloidal metal nanocrystals. The vast allure of this approach mainly stems from the staggering degree of control one can achieve over the size, shape, composition, and structure of nanocrystals. These parameters not only control the properties of nanocrystals but also determine their relevance to, and performance in, various applications. The ingenuity and artistry inherent to seed-mediated growth offer extensive promise, enhancing a number of existing applications and opening the door to new developments. This Review demonstrates how the diversity of metal nanocrystals can be expanded with endless opportunities by using seeds with well-defined and controllable internal structures in conjunction with a proper combination of capping agent and reduction kinetics. New capabilities and future directions are also highlighted.
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