期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 2, 页码 578-581出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201610291
关键词
composite membranes; in situ synthesis; Knoevenagel condensation; membrane reactors; metal-organic frameworks
资金
- MOE under AcRF Tier 2 [MOE2013-T2-1-034, MOE2014-T2-2-093, MOE2015-T2-2-057]
- MOE under AcRF Tier 1 [RG5/13]
- NTU under Start-Up Grant in Singapore [M4081296.070.500000]
The incorporation of metal-organic frameworks (MOFs) into membrane-shaped architectures is of great importance for practical applications. The currently synthesized MOF-based membranes show many disadvantages, such as poor compatibility, low dispersity, and instability, which severely limit their utility. Herein, we present a general, facile, and robust approach for the synthesis of MOF-based composite membranes through the in situ growth of MOF plates in the channels of anodized aluminum oxide (AAO) membranes. After being used as catalysis reactors, they exhibit high catalytic performance and stability in the Knoevenagel condensation reaction. The high catalytic performance might be attributed to the intrinsic structure of MOF-based composite membranes, which can remove the products from the reaction zone quickly, and prevent the aggregation and loss of catalysts during reaction and recycling process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据