期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 39, 页码 11840-11844出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201605880
关键词
B-H activation; carboranes; homogeneous catalysis; hydroxylation; rhodium
资金
- Research Grants Council of The Hong Kong Special Administration Region [14304115]
- Vice-Chancellor's (CUHK) Discretionary Fund
A rhodium-catalyzed hydroxylation of a cage B4-H bond in o-carboranes with either O-2 or air as the oxygen source is described, and serves as a new methodology for the regioselective generation of a series of 4-OH-o-carboranes in a one-pot process. The use of either O-2 or air as both the oxidant and the oxygen source makes this protocol very environmentally friendly and practical.
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