期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 18, 页码 5597-5601出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201510681
关键词
formic acid; hydrogen; phosphines; porous polymers; ruthenium
资金
- European Regional Development Fund (ERDF)
- state North Rhine-Westfalia, Germany, under the Operational Program Regional Competiveness and Employment
The co-production of formic acid during the conversion of cellulose to levulinic acid offers the possibility for on-site hydrogen production and reductive transformations. Phosphorus-based porous polymers loaded with Ru complexes exhibit high activity and selectivity in the base-free decomposition of formic acid to CO2 and H-2. A polymeric analogue of 1,2-bis(diphenylphosphino)ethane (DPPE) gave the best results in terms of performance and stability. Recycling tests revealed low levels of leaching and only a gradual decrease in the activity over seven runs. An applicability study revealed that these catalysts even facilitate selective removal of formic acid from crude product mixtures arising from the synthesis of levulinic acid.
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