期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 39, 页码 11765-11769出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201602849
关键词
amorphous calcium carbonate; bio-inspired synthesis; organic-inorganic hybrid composites; plasticity; supramolecular hydrogels
资金
- Alexander von Humboldt Foundation
- National Science Foundation of China [21431006, 21521001]
Given increasing environmental issues due to the large usage of non-biodegradable plastics based on petroleum, new plastic materials, which are economic, environmentally friendly, and recyclable are in high demand. One feasible strategy is the bio-inspired synthesis of mineral-based hybrid materials. Herein we report a facile route for an amorphous CaCO3 (ACC)-based hydrogel consisting of very small ACC nanoparticles physically cross-linked by poly(acrylic acid). The hydrogel is shapeable, stretchable, and self-healable. Upon drying, the hydrogel forms free-standing, rigid, and transparent objects with remarkable mechanical performance. By swelling in water, the material can completely recover the initial hydrogel state. As a matrix, thermochromism can also be easily introduced. The present hybrid hydrogel may represent a new class of plastic materials, the mineral plastics.
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