期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 37, 页码 11212-11216出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201604812
关键词
molybdenum; nitrogen fixation; Pligands; reduction; silanes
A homogeneous system which is able to yield silylamine from N-2 and bis(silane) in one pot is reported. Mechanistically a {(triphosphine)molybdenum(I)} fragment, generated in situ, splits N-2 into the corresponding nitrido complex at room temperature. Then, functionalization of the molybdenum nitrido is achieved by double Si-H addition under mild reaction conditions. Moreover, the bis(silyl)amine product is decoordinated from the metal center.
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