期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 29, 页码 8452-8456出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201604211
关键词
asymmetric catalysis; carbenes; heterocycles; insertion; rhodium
资金
- NSFC [21372086, 21422204]
- Guangdong NSF [2014A030313229]
- SRF for ROCS, State Education Ministry
- Fundamental Research Funds for the Central Universities, SCUT
- China Postdoctoral Science Foundation [2015M582378]
The first enantioselective intramolecular C-H insertion and cyclopropanation reactions of donor-and donor/donor-carbenes by a nondiazo approach are reported. The reactions were conducted in a one-pot manner without slow addition and provided the desired dihydroindole, dihydrobenzofuran, tetrahydrofuran, and tetrahydropyrrole derivatives with up to 99 % ee and 100 % atom efficiency.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据