期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 39, 页码 12054-12058出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201606330
关键词
alkynes; helicenes; photocyclodehydroiodination
资金
- National Science Foundation [CHE-495 1465142]
- NSF [CHE-1464955]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1464955] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1465142] Funding Source: National Science Foundation
A new approach to fused helicenes is reported, where varied substituents are readily incorporated in the extended aromatic frame. From the alkynyl precursor, the final helical compounds are obtained under mild conditions in a two-step process, in which the final C-C bond is formed via a photochemical cyclization/dehydroiodination sequence. The distortion of the p-system from planarity leads to unusual packing in the solid state. Computational analysis reveals that substituent incorporation perturbs geometries and electronic structures of these nonplanar aromatics.
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