期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 25, 页码 7227-7230出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201603235
关键词
amides; carbonylation; copper catalysis; cycloalkanes; imides
资金
- Chinese Scholarship Council
- NSFC [21472174]
- Zhejiang Natural Science Fund for Distinguished Young Scholars [LR16B020002]
Carbonylation reactions are a most powerful method for the synthesis of carbonyl-containing compounds. However, most known carbonylation procedures still require noble-metal catalysts and the use of activated compounds and good nucleophiles as substrates. Herein, we developed a copper-catalyzed carbonylative transformation of cycloalkanes and amides. Imides were prepared in good yields by carbonylation of a C(sp(3))-H bond of the cycloalkane with the amides acting as weak nucleophiles. Notably, this is the first report of copper-catalyzed carbonylative C-H activation.
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