期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 46, 页码 14448-14452出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201605838
关键词
boron; density functional theory; iron; pincer ligands; reduction
资金
- DFG [LA 2830/3-1]
- NSFC [21450110063]
- Studienstiftung des deutschen Volkes
Stabilized borylenes (L2BHD) with weakly pi-accepting substituents L, such as phosphines, were previously believed to be unstable. In the current manuscript, we describe a series of complexes formally containing a phosphine-stabilized borylene or boryl anion. In contrast to common trivalent boron compounds, the boron-based ligands in this study act as electron-donating ligands. The reported iron hydride complexes exhibit a unique reactivity pattern, undergoing a reversible B-H reductive elimination concomitant with oxidation of the boron(I) center.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据