期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 21, 页码 6315-6318出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201602130
关键词
aldehydes; alkenes; hydride transfer; iron; transfer hydrogenative couplings
资金
- National Natural Science Foundation of China [21402096, 21421062]
- Tianjin Applied Basic Research Project and Cutting-Edge Technology Research Plan [14JCYBJC41400]
- 1000-Youth Talents Plan
An FeBr3-catalyzed reductive coupling of various aldehydes with alkenes that proceeds through a direct hydride transfer pathway has been developed. With (PrOH)-Pr-i as the hydrogen donor under mild conditions, previously challenging coupling reactions of unactivated alkyl and aryl aldehydes with simple alkenes, such as styrene derivatives and alpha-olefins, proceeded smoothly to furnish a diverse range of functionalized alcohols with complete linear regioselectivity.
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