期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 13, 页码 4303-4307出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201511255
关键词
allyl boronates; allylic alcohols; allylic borylation; metal-free; polyboronates
资金
- Spanish Ministerio de Economia y Competitividad (MINECO) [CTQ2013-43395P]
- Swedish Reserach Council
- KAW foundation
The base-catalyzed allylic borylation of tertiary allylic alcohols allows the synthesis of 1,1-disubstituted allyl boronates, in moderate to high yield. The unexpected tandem performance of the Lewis acid-base adduct, [Hbase](+)[MeO-B(2)pin(2)](-) favored the formation of 1,2,3-triborylated species from the tertiary allylic alcohols and 1-propargylic cyclohexanol at 90 degrees C.
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