期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 10, 页码 3481-3485出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201511171
关键词
hydrogen bonds; phosphinamides; phosphorus heterocycles; self-assembly; soft materials
资金
- NSERC of Canada
- Canada Foundation for Innovation (CFI)
- Alberta Innovates-Technology Futures
A new, highly adaptable type of phosphinamide-based hydrogen bonding is representatively demonstrated in -conjugated phosphole materials. The rotational flexibility of these intermolecular P=O-H-N hydrogen bonds is demonstrated by X-ray crystallography and variable-concentration NMR spectroscopy. In addition to crystalline compounds, phosphinamide hydrogen bonding was successfully introduced into the self-assembly of soft crystals, liquid crystals, and organogels, thus highlighting the high general value of this type of interaction for the formation of organic soft materials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据