期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 31, 页码 8850-8855出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201511558
关键词
bimetallic nanoparticles; biomass; hydrodeoxygenation; mesoporous materials; phenols
资金
- European Commission [604307]
- Alexander von Humboldt Foundation
- Excellence Initiative by the German federal government
- Excellence Initiative by the German state government
Hydrodeoxygenation (HDO) is an attractive route for the upgrading of bio-oils produced from lignocellulose. Current catalysts require harsh conditions to effect HDO, decreasing the process efficiency in terms of energy and carbon balance. Herein we report a novel and facile method for synthesizing bimetallic PtCo nanoparticle catalysts (ca. 1.5 nm) highly dispersed in the framework of nitrogen-doped ordered mesoporous carbon (NOMC) for this reaction. We demonstrate that NOMC with either 2D hexagonal (p6m) or 3D cubic (Im (3) over barm) structure can be easily synthesized by simply adjusting the polymerization temperature. We also demonstrate that PtCo/NOMC (metal loading: Pt 9.90 wt%; Co 3.31 wt%) is a highly effective catalyst for HDO of phenolic compounds and real-world biomass-derived phenolic streams. In the presence of PtCo/NOMC, full deoxygenation of phenolic compounds and a biomass-derived phenolic stream is achieved under conditions of low severity.
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