期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 47, 页码 14653-14657出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201608345
关键词
amines; cobalt; nitriles; reductive amination; transfer hydrogenation
资金
- National Program for Thousand Young Talents of China
- 111 project
Herein, we describe a selective cobalt-catalyzed chemodivergent transfer hydrogenation of nitriles to synthesize primary, secondary, and tertiary amines. The solvent effect plays a key role for the selectivity control. The general applicability of this procedure was highlighted by the synthesis of more than 70 amine products bearing various functional groups in high chemoselectivity. Moreover, this mild system achieved >2000 TONs (turnover numbers) for the transfer hydrogenation of nitriles.
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