期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 41, 页码 12873-12876出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201607216
关键词
alkanes; bioinorganic chemistry; copper; homogeneous catalysis; oxidation
资金
- Robert A. Welch Foundation [N-1900]
Copper complexes bearing readily available ligand systems catalyzed the oxidation of alkanes with H2O2 as the oxidant with high efficiency in remarkable yields (50-60%). The reactions proceeded with unprecedented selectivity to give alkyl hydroperoxides as the major products. Detailed scrutiny of the reaction mechanism suggests the involvement of C-centered and O-centered radicals generated in a Fenton-like fashion.
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