期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 8, 页码 2743-2747出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201510533
关键词
fluorine; isocyanides; photoredox catalysis; radical reactions; sulfones
资金
- National Basic Research Program of China [2015CB931900, 2012CB821600]
- National Natural Science Foundation of China [21372246, 21421002, 21472221]
- Chinese Academy of Sciences, Shanghai Science and Technology program [15XD1504400]
- Syngenta Ph.D. Studentship
The radical fluoroalkylation of isocyanides with fluorinated sulfones is enabled by visible-light photoredox catalysis. A wide range of readily available mono-, di-, and trifluoromethyl heteroaryl sulfones can thus be used as efficient radical fluoroalkylation reagents under mild conditions. This method not only describes a new synthetic application of fluorinated sulfones, but also provides a new route to fluoroalkyl radicals.
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