期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 18, 页码 5414-5445出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201505581
关键词
CO2 reduction; H-2 generation; metal-organic frameworks; photocatalysis; solar fuels
资金
- Spanish Ministry of Economy and Competitiveness [CTQ-2015-69153-C2-1-R]
- Generalidad Valenciana [Prometeo 2013-014]
- European Community [228862]
- University Grants Commission, New Delhi
- Department of Science and Technology, India [SB/FT/CS-166/2013]
- Spanish Ministry of Economy and Competitiveness (Severo Ochoa)
Metal-organic frameworks (MOFs) are crystalline porous materials formed from bi- or multipodal organic linkers and transition-metal nodes. Some MOFs have high structural stability, combined with large flexibility in design and post-synthetic modification. MOFs can be photoresponsive through light absorption by the organic linker or the metal oxide nodes. Photoexcitation of the light absorbing units in MOFs often generates a ligand-to-metal charge-separation state that can result in photocatalytic activity. In this Review we discuss the advantages and uniqueness that MOFs offer in photocatalysis. We present the best practices to determine photocatalytic activity in MOFs and for the deposition of co-catalysts. In particular we give examples showing the photocatalytic activity of MOFs in H-2 evolution, CO2 reduction, photooxygenation, and photoreduction.
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