期刊
ADVANCED ENERGY MATERIALS
卷 9, 期 16, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201900091
关键词
anode material; cobalt phosphide; sodium-ion capacitors; tin; yolk-shell
类别
资金
- National Natural Science Foundation of China [51572100, 21875080, 51504171, 61434001]
- Major Project of Technology Innovation of Hubei Province [2018AAA011]
- HUST Key Interdisciplinary Team Project [2016JCTD101]
- Wuhan Yellow Crane Talents Program
- City University of Hong Kong Strategic Research Grant (SRG) [7005105]
Sodium-ion capacitors (SICs) are emerging energy storage devices with high energy, high power, and durable life. Sn is a promising anode material for lithium storage, but the poor conductivity of the a-NaSn phase upon sodaition hinders its implementation in SICs. Herein, a superior Sn-based anode material consisting of plum pudding-like Co2P/Sn yolk encapsulated with nitrogen-doped carbon nanobox (Co2P/Sn@NC) for high-performance SICs is reported. The 8-10 nm metallic nanoparticles produced in situ are uniformly dispersed in the amorphous Sn matrix serving as conductive fillers to facilitate electron transfer in spite of the formation of electrically resistive a-NaSn phase during cycling. Meanwhile, the carbon shell buffers the large expansion of active Sn and provides a stable electrode-electrolyte interface. Owing to these merits, the yolk-shell Co2P/Sn@NC demonstrates a large capacity of 394 mA h g(-1) at 100 mA g(-1), high rate capability of 168 mA h g(-1) at 5000 mA g(-1), and excellent cyclability with 87% capacity retention after 10 000 cycles. By integrating the Co2P/Sn@NC anode with a peanut shell-derived carbon cathode in the SIC, high energy densities of 112.3 and 43.7 Wh kg(-1) at power densities of 100 and 10 000 W kg(-1) are achieved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据