期刊
ACS CATALYSIS
卷 9, 期 4, 页码 3054-3058出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b00287
关键词
C-C bond formation; hydrogen atom transfer; photocatalysis; radical reactions; uranyl cation
资金
- MIUR [RBSI145Y9R]
Uranyl nitrate hexahydrate performs as an efficient photo catalyst in the direct C-H to C-C bond conversion under blue light irradiation via hydrogen atom transfer (HAT). This uranyl salt enables the remarkable smooth functionalization of unactivated (cyclo)alkanes, ethers, acetals, and amides via radical addition onto electrophilic olefins. Dedicated electrochemical measurements on compounds and intermediates involved in the process were carried out to support the mechanistic proposal.
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