Ultrathin, Polycrystalline, Two-Dimensional Co3O4 for Low-Temperature CO Oxidation

Free-standing, hierarchical, ultrathin, and two-dimensional (2D) polycrystalline Co3O4 flowers were synthesized by a hydrothermal and topotactic transformation process. Aberration-corrected electron microscopy study of both the CoOx precursor structure and the subsequent topotactic transformation processes revealed the nucleation and growth mechanisms of the 2D polycrystalline Co3O4 nanosheets. The free-standing flower-shaped CoOx powders (1-5 mu m) consist of numerous self-assembled nano-crystallites (average size similar to 1.8 nm). After the topotactic transformation, via a rapid calcination process, the powders maintained their hierarchical flower-like shape, but the CoOx nanocrystallites structurally transformed into ultrathin 2D Co3O4 nanoplates with thicknesses ranging from 1 to 5 nm (average thickness similar to 2.4 nm). The final, free-standing, ultrathin 2D polycrystalline Co3O4 flowers possess a BET surface area of 138 m(2)/g. Statistical structural analyses revealed that the exposed surfaces of the Co3O4 flowers are dominated by the Co3O4{112} (similar to 70%). The hierarchical Co3O4 flowers contain many grain boundaries, pockets, surface steps, and other types of surface defects. CO oxidation on the as-synthesized hierarchical Co3O4 flowers showed a specific activity (normalized to the surface area) of 0.377 mu mol.m(-2).s(-1), about 5 times that of the most active Co3O4 at 70 degrees C reported in literature. Furthermore, even under moisture-saturated condition (similar to 3% H2O), the ultrathin 2D Co3O4 catalyst demonstrated a high specific rate and is stable for at least 40 h at 90 and 150 degrees C. The abundance of accessible coordinatively unsaturated Co3+, active oxygen species, and surface defects on the polycrystalline Co3O4{112} nanosheets are responsible for the experimentally observed high catalytic activity.