期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 41, 页码 12812-12816出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201607221
关键词
bismuth sulfide; inorganic crystals; morphogenesis; poly(ionic liquid)s; polymer-controlled crystallization
资金
- Max Plank Society
- CAS Pioneer Hundred Talents Program
- National Natural Science Foundation of China [21431006]
- Foundation for Innovative Research Groups of the National Natural Science Foundation of China [21521001]
- National Basic Research Program of China [2014CB931800, 2013CB931800]
- European Research Council [639720-NAPOLI]
Conventional polymer additives have a substantial impact on synthetic inorganic chemistry, but critical shortcomings remain; for example, low solubility in organic solvents and potential thermodynamic aggregates. Poly(ionic liquid)s have now been used as efficient additives that enable a high level control of bismuth sulfide crystals with significant size and morphological diversities. The bismuth sulfides exhibit tunable band structure as a result of the quantum size effects. Moreover, poly(ionic liquid)s are able to couple with as-synthesized bismuth sulfides chemically and endow a modified surface electronic structure, which allows resultant products to possess outstanding electrocatalytic performance for water oxidation, although its commercial counterpart is catalytically inert.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据